STUDIES IN OPTICAL ROTATORY DISPERSION AND CIRCULAR DICHROISM .11. A QUADRANT RULE FOR N-]PI(')-COTTON EFFECTS IN DITHIOCARBAMATES AND DITHIOURETHANES OF CHIRAL AMINES

被引：16

作者：

RIPPERGER, H

机构：

来源：

TETRAHEDRON | 1969年 / 25卷 / 04期

关键词：

D O I：

10.1016/0040-4020(69)85004-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several asymmetric dithiocarbamates and dithiourethanes were synthesized and their n → π* Cotton effects were measured. A simple quadrant rule is given predicting the sign of these Cotton effects. This rule is useful in solving stereochemical problems in a manner analogous to the octant rule for ketones. © 1969.

引用

页码：725 / +

页数：1

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