THEORETICAL ASPECTS OF COUPLING MODEL SCHEMES OF SLOW RELAXATION IN COMPLEX CORRELATED SYSTEMS

被引:42
作者
RAJAGOPAL, AK
NGAI, KL
TEITLER, S
机构
[1] Naval Research Laboratory, Washington
关键词
D O I
10.1016/0022-3093(91)90317-Y
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Experimental data of temporal relaxation phenomena in diverse types of complex correlated condensed matter systems seem to follow stretched exponential behavior (or its frequency space counterpart). Descriptions of such phenomena based on 'coupling model' schemes invoke three timescales: tau-0 associated with an early linear exponential; tau* associated with a late stretched exponential with a stretching index n (0 less-than-or-equal-to n < 1); and omega-c-1, the time of onset of the effect of coupling (correlation) which enters into a relation between tau-0 and tau*, namely, omega-c-tau* = [(1 - n)-omega-c-tau-0]1/1 - n. Tau-0 represents the relaxation time before correlations become operative and tau* is the relaxation time when correlations are operative. 'Coupling model' schemes described here have been successful in bringing together a large body of experimental data for a significant class of complex correlated systems (CCS) and demonstrate certain widely shared behaviors. A review of the conceptual notions used in coupling model schemes in the past decade is outlined. The scope and underlying assumptions of these schemes are made explicit. In an appendix, a general phenomenology that brings out the dynamic structure of relaxation in CCS is also outlined.
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页码:282 / 288
页数:7
相关论文
共 23 条
[1]   TRANSPORT OF DISORDERED STRUCTURES - EFFECT OF LONG-RANGE INTERACTIONS [J].
BUNDE, A ;
MAASS, P ;
ROMAN, HE ;
DIETERICH, W ;
PETERSEN, J .
SOLID STATE IONICS, 1990, 40-1 :187-191
[2]   MONTE-CARLO STUDIES ON THE LONG-TIME DYNAMIC PROPERTIES OF DENSE CUBIC LATTICE MULTICHAIN SYSTEMS .1. THE HOMOPOLYMERIC MELT [J].
KOLINSKI, A ;
SKOLNICK, J ;
YARIS, R .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (12) :7164-7173
[3]   DYNAMICS OF ENTANGLED LINEAR POLYMER MELTS - A MOLECULAR-DYNAMICS SIMULATION [J].
KREMER, K ;
GREST, GS .
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (08) :5057-5086
[4]   NON-DEBYE RELAXATION IN STRUCTURALLY DISORDERED IONIC CONDUCTORS - EFFECT OF COULOMB INTERACTION [J].
MAASS, P ;
PETERSEN, J ;
BUNDE, A ;
DIETERICH, W ;
ROMAN, HE .
PHYSICAL REVIEW LETTERS, 1991, 66 (01) :52-55
[5]  
Ngai K. L., 1979, Comments on Solid State Physics, V9, P127
[6]  
Ngai K. L., 1988, Nuclear Physics B, Proceedings Supplements, V5A, P103, DOI 10.1016/0920-5632(88)90022-9
[7]  
Ngai K. L., 1980, Comments on Solid State Physics, V9, P141
[8]  
Ngai K. L., 1986, ANN NY ACAD SCI, V484, P150
[9]   DISPERSIVE DIFFUSION TRANSPORT AND NOISE, TIME-DEPENDENT DIFFUSION-COEFFICIENT, GENERALIZED EINSTEIN-NERNST RELATION, AND DISPERSIVE DIFFUSION-CONTROLLED UNIMOLECULAR AND BIOMOLECULAR REACTIONS [J].
NGAI, KL ;
LIU, FS .
PHYSICAL REVIEW B, 1981, 24 (02) :1049-1064
[10]   RELAXATION PHENOMENA AND STABILITY OF PROBABILITY DENSITIES [J].
NGAI, KL ;
RAJAGOPAL, AK ;
TEITLER, S .
PHYSICA A, 1985, 133 (1-2) :213-227