OXIDATION OF ALKENES USING THE RUCL3/PHIO SYSTEM

被引：9

作者：

AGARWAL, DD

JAIN, R

CHAKRAVORTY, A

RASTOGI, R

机构：

[1] School of Studies in Chemistry, Jiwaji University, Gwalior

来源：

POLYHEDRON | 1992年 / 11卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)83203-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The RuCl3 catalysed epoxidation of olefins gave more than 10% of epoxide. Pyridine addition increased the yield and selectivity of the epoxide. Epoxidation of norbornene gave exo- and endo-epoxide. The effect of surfactants supports the involvement of carbocation intermediates. The epoxidation of cyclic olefins follows the reactivity order cyclo-octene > norbornene > cyclopentene > cycloheptene > cyclohexene. Spectral studies suggest that oxo ruthenium(V) is the active oxidizing species.

引用

页码：463 / 467

页数：5

共 34 条

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