A REFLECTION SPECTROSCOPIC STUDY OF SURFACE PRESSURE-GRADIENTS IN MONOLAYERS OF LONG-CHAIN FATTY-ACIDS

被引:4
作者
DHATHATHREYAN, A [1 ]
MOBIUS, D [1 ]
机构
[1] MAX PLANCK INST BIOPHYS CHEM,D-37077 GOTTINGEN,GERMANY
关键词
D O I
10.1006/jcis.1995.1264
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Compression of long chain fatty acids generates gradients in surface pressure similar to but smaller than those reported previously for polymer monolayers. These have been investigated by reflection spectroscopy and surface pressure measurements for the monolayers at the air/water interface. The gradient increases sharply in the condensed state and is dependent on the chain length of the compounds chosen. The spreading as well as the compression techniques affect the gradient formation and a pressure gradient implying inhomogenity in the monolayer is always present. (C) 1995 Academic Press, Inc.
引用
收藏
页码:358 / 360
页数:3
相关论文
共 19 条
[1]  
Gaines G.L., Insoluble Monolyers at Liquid-Gas Interfaces, (1966)
[2]  
Kjaer K., Als-Nielson J., Helm C.A., Tippman-Krayer P., Moh-Wald H., J. Phys. Chem, 93, (1989)
[3]  
Kajiyama T., Tanimoto Y., Uchida M., Oishi Y., Takei R., Chem. Lett, (1989)
[4]  
Jyeda N., Takenaka T., Aoyama K., Matsumoto M., Fujiyoshi Y., Nature, 327, (1987)
[5]  
Kajiyama T., Oishi Y., Uchida M., Morotomi Ishikawa N.J., Tanimoto Y., Bull. Chem. Soc. Jpn, 65, (1992)
[6]  
Hunt R.D., Mitchell M.L., Dluhy R.A., J. Mol. Struct, 214, (1989)
[7]  
Kajiyama T., Oishi Y., Uchida M., Tanimoto Y., Kozuru H., Langmuir %, (1992)
[8]  
Vollhardt D., Zastrow L., Wustneck R., Colloid Polym. Sei, 973, (1978)
[9]  
Vollhardt Zastrow D.L., Wustneck R., Colloid Polym. Sei, 256, (1978)
[10]  
Dhathathreyan Baumann A.U., Muller A., Mobius D., Biochim. Biophys. Acta, 944, (1988)