A VARIABLE TEMPERATURE H-1-NMR STUDY OF STEREOCHEMICAL NON-RIGIDITY IN GROUP-VI METAL PENTACARBONYL COMPLEXES OF 1,3,5,7-TETRATHIAN - [M(CO)5(SCH2SCH2SCH2SCH2)] (M = CR OR W)

被引：15

作者：

ABEL, EW ^{[1
]}

KING, GD ^{[1
]}

ORRELL, KG ^{[1
]}

SIK, V ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

来源：

POLYHEDRON | 1983年 / 2卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)84400-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1363 / 1370

页数：8

共 31 条

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[3] A DYNAMIC NUCLEAR MAGNETIC-RESONANCE STUDY OF 1,3-INTRAMOLECULAR SHIFTS IN PENTA-CARBONYL-CHROMIUM(O) AND -TUNGSTEN(O) COMPLEXES OF BETA-2,4,6-TRIMETHYL-1,3,5-TRITHIAN, 1,3,5-TRITHIAN, 1,3-DITHIAN AND 2-METHYL-1,3-DITHIAN - THE X-RAY CRYSTAL-STRUCTURE OF [W(CO)5(SCH(ME)SCH(ME)SCH(ME))] [J].

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[4] NUCLEAR MAGNETIC-RESONANCE STUDY OF INVERSION AT SULFUR AND SELENIUM ATOMS IN COMPLEXES OF PALLADIUM(II) AND PLATINUM(II) .1. COMPLEXES OF BIS(TRIMETHYLSIYLMETHYL) SULFIDE AND SELENIDE [J].

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[5] DETERMINATION OF THE SEPARATE BARRIER ENERGIES FOR 6-MEMBERED LIGAND RING REVERSAL AND PYRAMIDAL SULFUR INVERSION IN COMPLEXES OF PALLADIUM(II) AND PLATINUM(II) - A DYNAMIC H-1 AND C-13 NUCLEAR MAGNETIC-RESONANCE STUDY [J].

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[6] RING REVERSAL, SULFUR INVERSION, AND 1,3-METAL SHIFTS IN SULFUR-CONTAINING SIX-MEMBERED-RING COMPLEXES OF CHROMIUM AND TUNGSTEN CARBONYLS [J].

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[7]

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[8] EFFECT OF VARIATION IN LIGAND RING SIZE UPON THE INVERSION BARRIER AT SULFUR IN COMPLEXES OF PALLADIUM(II) AND PLATINUM(II) - DYNAMIC H-1 NUCLEAR MAGNETIC-RESONANCE STUDY [J].

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[9] 1,3-INTRAMOLECULAR METAL SHIFTS IN PENTACARBONYLTUNGSTEN(0) COMPLEXES OF 2,4-DITHIAPENTANE, 2,4-DISELENAPENTANE, AND 2-SELENA-4-THIAPENTANE [J].

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