GAMMA-(PHENYLTHIO)ALLYL AND ALLENYLSTANNANES AS UNSATURATED THIONIUM ION EQUIVALENTS

被引：15

作者：

TAKEDA, T

NAKAYAMA, A

FURUKAWA, T

FUJIWARA, T

机构：

[1] Department of Applied Chemistry, Tokyo University of Agriculture and Technology, Koganei, Tokyo

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)97147-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of trimethylsilyl enol ethers with γ-(phenylthio)allyl and allenylstannanes in the presence of tin (IV) or copper(II) salt proceeded regioselectively to give the coupling products, which in turn were transformed to 2-cyclohexenones and 1-alken-3-ynyl ketones by simple treatment with hydrochloric acid or oxone/DBU, respectively. © 1990.

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页码：6685 / 6688

页数：4

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