HYDROBORATION AMINATION OF N-TRIMETHYLSILY PROTECTED OLEFINIC AMINES AND DIOLEFINS - SYNTHESIS OF ISOMERICALLY PURE DIAMINES

被引：7

作者：

KABALKA, GW

WANG, Z

机构：

[1] UNIV TENNESSEE, DEPT CHEM, KNOXVILLE, TN 37996 USA

[2] UNIV TENNESSEE, DEPT RADIOL, KNOXVILLE, TN 37996 USA

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 14期

关键词：

D O I：

10.1080/00397919008053146

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Trimethylsilyl protected olefinic amines and terminal diolefins were hydroborated with dimethylborane and the resulting organoboranes were treated with in situ generated chloramine or chloroalkylamines to produce isomerically pure diamines or N-substituted diamines in good yields. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：2113 / 2118

页数：6

共 14 条

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[8] PREPARATION OF ISOMERICALLY PURE ALKYLAMINES VIA THE REACTION OF DIMETHYLALKYLBORANES WITH CHLORAMINE
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[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (13-14) : 2409 - 2414
[9] THE SYNTHESIS OF RADIOLABELED COMPOUNDS VIA ORGANOMETALLIC INTERMEDIATES
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[10] PREPARATION OF ISOMERICALLY PURE DIALKYLAMINES VIA THE REACTION OF DIMETHYLALKYLBORANES WITH CHLOROALKYLAMINE
KABALKA, GW
WANG, Z
[J]. SYNTHETIC COMMUNICATIONS, 1990, 20 (02) : 231 - 237

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