PREPARATION OF CYCLOHEXENYL DERIVATIVES BY THE RING-OPENING REACTIONS OF OXABICYCLO[2.2.1] COMPOUNDS WITH CUPRATES

被引:25
作者
LAUTENS, M
SMITH, AC
ABDELAZIZ, AS
HUBOUX, AH
机构
[1] Department of Chemistry, University of Toronto, Toronto
关键词
D O I
10.1016/S0040-4039(00)89036-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The ring-opening reaction of 7-oxabicyclo[2.2.1]hept-5-enes with cuprates is described. SN2′ attack with retention of configuration is the predominant pathway. © 1990.
引用
收藏
页码:3253 / 3256
页数:4
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