A NOVEL SYNTHESIS OF (OXODIMETHYLENEMETHANE)-PALLADIUM AND (OXODIMETHYLENEMETHANE)-PLATINUM COMPLEXES

被引:23
作者
OHSUKA, A [1 ]
FUJIMORI, T [1 ]
HIRAO, T [1 ]
KUROSAWA, H [1 ]
IKEDA, I [1 ]
机构
[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN
关键词
D O I
10.1039/c39930001039
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of pi-allyl-palladium and -platinum complexes bearing a methoxymethoxy group at the 2-position with base give the corresponding oxodimethylenemethane complexes, in contrast to the formation of 2-hydroxy-substituted pi-allyl complexes via acidic hydrolysis.
引用
收藏
页码:1039 / 1040
页数:2
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