ORIGIN OF HIGH REACTIVITY OF PEROXIDE ADDUCT OF MANGANESE(III) SCHIFF-BASE COMPLEXES TOWARDS ORGANIC-ACID ANHYDRIDES

被引：13

作者：

NISHIDA, Y

TAKAHASHI, S

WATANABE, I

YAMAZAKI, A

ITOH, H

SAKAMOTO, M

机构：

[1] Department of Chemistry, Faculty of Science, Yamagata University, Yamagata

来源：

POLYHEDRON | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)83448-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of the peroxide adducts of manganese(III) Schiff base complexes towards several organic compounds was investigated by means of electrochemical methods and the results were interpreted in terms of molecular orbital calculations for both the metal peroxide adduct and the organic compound. Based on these results, the importance of the electrophilic nature of the peroxide adduct and the electron distribution in the frontier orbital of organic acid anhydride moiety was stressed in order to explain the high reactivity between the two compounds.

引用

页码：1539 / 1545

页数：7

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