OXIDATIVE HOMOPOLYMERIZATION AND COPOLYMERIZATION OF SUBSTITUTED CARBAZOLE AND THIOPHENE

被引：19

作者：

SIOVE, A ^{[1
]}

DAVID, R ^{[1
]}

ADES, D ^{[1
]}

ROUX, C ^{[1
]}

LECLERC, M ^{[1
]}

机构：

[1] UNIV MONTREAL,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1995年 / 92卷 / 04期

关键词：

D O I：

10.1051/jcp/1995920787

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Chemical oxidation of N-ethylcarbazole by FeCl3 quantitatively yields dimer. Oxidation is the rate-determining step among the three elementary reactions involved in the process, Oxidation of 3-octylthiophene in the same conditions, leads to the formation very rapidly of high molecular weights through the coupling of oligomeric active species. Copolymerization of the monomers by FeCl3 gives rise to materials whose solubility and thermochromism depend on the composition and therefore can be tuned.

引用

页码：787 / 790

页数：4

共 6 条

[1] ANODIC OXIDATION PATHWAYS OF CARBAZOLES .1. CARBAZOLE AND N-SUBSTITUTED DERIVATIVES [J].