DEMONSTRATION OF A SHELL CORE STRUCTURE IN LAYERED CDSE-ZNSE SMALL PARTICLES BY X-RAY PHOTOELECTRON AND AUGER SPECTROSCOPIES

被引:232
作者
HOENER, CF [1 ]
ALLAN, KA [1 ]
BARD, AJ [1 ]
CAMPION, A [1 ]
FOX, MA [1 ]
MALLOUK, TE [1 ]
WEBBER, SE [1 ]
WHITE, JM [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712
关键词
D O I
10.1021/j100188a045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preferential positioning of different cations near the surface or at the center of small layered CdSe-ZnSe particles believed to have a shell-core structure has been demonstrated by the relative attenuation of the primary photoelectron and X-ray excited Auger signals from each cation. The preparation of the layered particles is described, and their absorption spectra are compared with those observed in "unstructured" particles of like composition.
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页码:3812 / 3817
页数:6
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