NOVEL SYNTHESIS OF 5,10,15,20-TETRAARYLPORPHYRINS USING HIGH-VALENT TRANSITION-METAL SALTS

被引：26

作者：

GRADILLAS, A ^{[1
]}

DELCAMPO, C ^{[1
]}

SINISTERRA, JV ^{[1
]}

LLAMA, EF ^{[1
]}

机构：

[1] UNIV COMPLUTENSE MADRID,FAC PHARM,DEPT ORGAN & PHARMACEUT CHEM,E-28040 MADRID,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 20期

关键词：

D O I：

10.1039/p19950002611

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthesis of porphyrins from pyrrole and substituted benzaldehydes, is described, using high-valent transition metal salts [VOCl3, VO(OEt)Cl-2, VO(OPri)Cl-2, TiCl4 and Mn(OAc)(3)] as aromatizing agents. This process allows higher working concentrations and larger amounts of reagent to be used, than those previously described.

引用

页码：2611 / 2613

页数：3

共 30 条

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