AN EXTREMELY MILD 3-AZA-CLAISEN REACTION .1. REARRANGEMENT OF SIMPLE N-ALLYL AMIDES

被引：26

作者：

WALTERS, MA

MCDONOUGH, CS

BROWN, PS

HOEM, AB

机构：

[1] Department of Chemistry, Dartmouth College, Hanover

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 02期

关键词：

D O I：

10.1016/0040-4039(91)80848-Z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An extremely mild 3-aza-Claisen reaction has been developed. Readily available N-allyl amides are converted to pentenylnitriles in moderate to good yields by a transformation that occurs at room temperature under essentially neutral conditions.

引用

页码：179 / 182

页数：4

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