PHOTOELECTRON-SPECTRA, ORBITAL INTERACTION, AND CONFORMATIONS OF ALKYLALKENYLCYCLOPROPANES AND ALKYLALKENYLCYCLOPROPENES

被引：7

作者：

PLEMENKOV, VV

BUTENKO, OJ

ZVEREV, VV

ERMOLAEVA, LV

VAKAR, VM

IGNATCHENKO, AV

BOLESOV, IG

机构：

[1] KAZAN ORGAN & PHYS CHEM,KAZAN 420083,USSR

[2] MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 117234,USSR

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 218卷

关键词：

D O I：

10.1016/0022-2860(90)80266-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ionization potentials (IP) of the 1-methyl-1-alkenylcyclopropanes and 3-methyl-3-alkenylcyclopropenes were measured by Photoelectron Spectroscopy (PES). The conformations of these molecules were calculated by MO (AM-1) method. It was concluded that orthogonal conformations (goch) are more characteristic in the series of alkenylcyclopropanes, meanwhile in the series of alkenylcyclopropenes symmetric forms (cis or trans) are more possible. © 1990.

引用

页码：195 / 200

页数：6

共 8 条

[1]

BATICH C, 1974, TETRAHEDRON LETT, P1467

[2]

GLEITER R, 1979, TOP CURR CHEM, V86, P197

[3] PHOTOELECTRON-SPECTRA OF HYDRAZINES .3. EVIDENCE FOR SIMILAR LONE PAIR-LONE PAIR DIHEDRAL ANGLES FOR ACYCLIC HYDRAZINES [J].