STEREOCHEMISTRY OF HYDROGEN-DEUTERIUM EXCHANGES OF BENZYLIC PROTONS OF ARENETRICARBONYLCHROMIUM - EXCHANGE OF METAL SYN-PROTONS

被引：2

作者：

BROCARD, J

PELINSKI, L

GOETGHELUCK, S

MACIEJEWSKI, L

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 456卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80446-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetralintricarbonylchromium exchanges anti and syn benzylic protons in a solution of potassium tert-butoxide DMSO-d6. Under the same conditions the syn benzylic tertiary proton of trans-1-methyltetralintricarbonylchromium remains unchanged. The anti and syn benzylic protons of dihydroanthracenetricarbonylchromium and xanthenetricarbonylchromium undergo exchange and trans-9-methyl xanthenetricarbonylchromium undergoes exchange and epimerisation.

引用

页码：C24 / C26

页数：3

共 6 条

[1] BOUDEVILLE M, 1975, TETRAHEDRON LETT, V32, P2727
[2] BENZYL FUNCTION IN ARENETRICARBONYLCHROMIUM SERIES, ELECTRONIC CONTROL OF THE REGIOSPECIFICITY OF REACTIONS
BROCARD, J
LEBIBI, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 320 (03) : 295 - 306
[3] SUBSTITUENT EFFECTS IN BENZYLIC FUNCTIONALIZATION OF ARENE(TRICARBONYL) CHROMIUM COMPLEXES
BROCARD, J
LACONI, A
COUTURIER, D
TOP, S
JAOUEN, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (07) : 475 - 476
[4] JAOUEN G, 1984, J AM CHEM SOC, V106, P2208
[5] Solladie-Cavallo A, 1989, ADV METAL ORGANIC CH, V1, P99
[6] ARENE-METAL COMPLEXES .4. BASE-CATALYZED STEREOSELECTIVE HYDROGEN-DEUTERIUM EXCHANGE OF BENZYLIC PROTONS OF TRICARBONYLCHROMIUM(0)-COMPLEXED ALKYLBENZENES
TRAHANOVSKY, WS
CARD, RJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (08) : 2897 - +

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