TITANIUM-DIOXIDE PHOTOCATALYZED OXIDATION OF BENZYLTRIMETHYLSILANES IN THE PRESENCE OF SILVER SULFATE

被引：39

作者：

BACIOCCHI, E ^{[1
]}

ROL, C ^{[1
]}

ROSATO, GC ^{[1
]}

SEBASTIANI, GV ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of Ag2SO4, the TiO2-mediated photochemical oxidation of substituted benzyltrimethylsilanes in acetonitrile leads to diarylethanes (50-74%) with a significant intermolecular selectivity (rho = -2.5).

引用

页码：59 / 60

页数：2

共 10 条

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[4] SELECTIVITY IN THE TIO2-MEDIATED PHOTOCATALYTIC OXIDATION OF THIOETHERS
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[J]. TETRAHEDRON LETTERS, 1990, 31 (32) : 4533 - 4536
[5] FOX MA, 1989, PHOTOCATALYSIS FUNDA, pCH13
[6] FUJIHARA M, 1981, J ELECTROANAL CH INF, V186, P277
[7] INABA S, 1984, J ORG CHEM, V49, P2097
[8] PYROLYSIS OF DIBENZYL SELENIDES TO BIBENZYLS
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[J]. SYNTHETIC COMMUNICATIONS, 1980, 10 (08) : 595 - 601
[9] PICHAT P, 1988, PHOTOINDUCED ELECT D, pCH6
[10] WONG CM, 1990, J AM CHEM SOC, V112, P2016

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