SYNTHESIS AND PROPERTIES OF FLUOROTHALLIUM(III) PORPHYRINS - X-RAY CRYSTAL-STRUCTURE OF FLUORO-(5,10,15,20-TETRAPHENYLPORPHYRINATO) THALLIUM(III)

被引：11

作者：

COUTSOLELOS, AG ^{[1
]}

ORFANOPOULOS, M ^{[1
]}

WARD, DL ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

POLYHEDRON | 1991年 / 10卷 / 09期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86905-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The action of sodium fluoride on chlorothallium(III) porphyrins, Tl(Por)Cl, produces the corresponding fluoroporphyrins, Tl(Por)F. These complexes were characterized by their H-1-NMR, UV-vis and IR data. The crystal structures of the title compound [Tl(TPP)F] has been determined by X-ray diffraction. It crystallizes in the monoclinic space group P2(1)/n with Z = 4 and lattice dimensions a = 10.118(3), b = 16.236(5), c = 21.189(6) angstrom, beta = 90.86(2)-degrees, V = 3480(2) angstrom 3. C44H28FN4Tl, F(w) = 836.11 g, rho = 1.60 g cm-3, mu = 47.3 cm-1, F(000) = 1640, temperature 23(1)-degrees-C, R(F) = 0.045, Rw(F) = 0.050 for 2135 observed reflections. The thallium-fluorine distance is 2.441(6) angstrom with the thallium atom situated 0.741(1) angstrom above the porphyrin ring.

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页码：885 / 892

页数：8

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