A COMPARISON OF SOME COMPLEXES OF THE TYPE EQ-[MN2(CO)9L], WHERE L IS A CYCLIC CARBENE LIGAND WITH A 5-MEMBERED OR 6-MEMBERED RING AND THE MOLECULAR-STRUCTURES OF 2 COMPLEXES CONTAINING 6-MEMBERED CARBENE RINGS

被引：8

作者：

ANDERSEN, JAM ^{[1
]}

ARCHER, SJ ^{[1
]}

MOSS, JR ^{[1
]}

NIVEN, ML ^{[1
]}

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

INORGANICA CHIMICA ACTA | 1993年 / 206卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)82865-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new five-membered ring cyclic carbene complexes eq-[Mn2(CO)9L] (where L = CCH2CH(CH3)CH2O or CC(CH3)2CH2CH2O) have been prepared and characterized. Thermal analysis and H-1/2D exchange experiments are compared for several five- and six-membered ring cyclic carbene complexes of the type eq-[Mn2(CO)9L]. The X-ray crystal structures of the six-membered ring carbene complexes eq-[Mn2(CO)9L] (where L = CCH2CH2CH2CH2O and CCH2CH2CH2CH(CH3)O) have been determined and are compared with the known structures of the related five-membered ring complexes.

引用

页码：187 / 192

页数：6

共 21 条

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