SYNTHESIS AND CHARACTERIZATION OF THE LUTETIUM NAPHTHALENE COMPLEX, CPLUC10H8(DME)

被引：46

作者：

PROTCHENKO, AV

ZAKHAROV, LN

BOCHKAREV, MN

STRUCHKOV, YT

机构：

[1] RUSSIAN ACAD SCI, INST ORGANOMET CHEM, NIZHNII NOVGOROD, RUSSIA

[2] AN NESMEYANOV INST ORGANOELEMENT CPDS, MOSCOW, RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 447卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80240-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound (1) was obtained as black diamagnetic crystals by reaction of CpLuCl2 with sodium naphthalide in DME. The naphthalene moiety in 1 is bent about the C(1) ... C(4) plane (dihedral angle 148.5-degrees). The Lu-C(C10H8) bond lengths and redistribution of C-C bond distances in the coordinated naphthalene ring suggest 2eta1 : eta2-interaction of the Lu atom with the naphthalene moiety.

引用

页码：209 / 212

页数：4

共 10 条

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