PHOTOELECTRON AND OPTICAL SPECTROSCOPIC INVESTIGATIONS OF THE ELECTRONIC-STRUCTURE OF OLIGO(P-PHENYLENEVINYLENE)S IN THE SOLID-STATE

被引:30
作者
SCHMIDT, A [1 ]
ANDERSON, ML [1 ]
DUNPHY, D [1 ]
WEHRMEISTER, T [1 ]
MULLEN, K [1 ]
ARMSTRONG, NR [1 ]
机构
[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721
关键词
D O I
10.1002/adma.19950070808
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: The performance of organic light-emitting diodes based, for example, on poly(p-phenylenevinylene) could be more easily optimized on the basis of a thorough knowledge of the energies of the electron affinities and the ionization potentials of the materials. Here, results from UV-photoelectron spectroscopy are presented which allow the determination of the absolute binding energies of the occupied molecular orbitals of oligo-PPV. These results are compared with values calculated using semiempirical methods.
引用
收藏
页码:722 / 726
页数:5
相关论文
共 26 条
[1]  
ADAMSON AW, 1979, TXB PHYSICAL CHEM, P669
[2]  
BORROUGHES JH, 1990, NATURE, V347, P539
[3]   ABINITIO EFFECTIVE HAMILTONIAN STUDY OF THE ELECTRONIC-PROPERTIES OF CONJUGATED POLYMERS [J].
BREDAS, JL ;
CHANCE, RR ;
BAUGHMAN, RH ;
SILBEY, R .
JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (07) :3673-3678
[4]   EXCITONS IN POLY(PARA-PHENYLENEVINYLENE) [J].
CHANDROSS, M ;
MAZUMDAR, S ;
JEGLINSKI, S ;
WEI, X ;
VARDENY, ZV ;
KWOCK, EW ;
MILLER, TM .
PHYSICAL REVIEW B, 1994, 50 (19) :14702-14705
[5]   EXCITONS AND THE BAND-GAP IN POLY(PHENYLENE VINYLENE) [J].
DACOSTA, PG ;
CONWELL, EM .
PHYSICAL REVIEW B, 1993, 48 (03) :1993-1996
[6]   GROUND-STATES OF MOLECULES .39. MNDO RESULTS FOR MOLECULES CONTAINING HYDROGEN, CARBON, NITROGEN, AND OXYGEN [J].
DEWAR, MJS ;
THIEL, W .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :4907-4917
[7]   GROUND-STATES OF MOLECULES .38. MNDO METHOD - APPROXIMATIONS AND PARAMETERS [J].
DEWAR, MJS ;
THIEL, W .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :4899-4907
[8]   THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].
DEWAR, MJS ;
ZOEBISCH, EG ;
HEALY, EF ;
STEWART, JJP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909
[9]  
FAHLMAN M, 1993, SYNTHETIC MET, V55, P263, DOI 10.1016/0379-6779(93)90943-Q
[10]   RAMAN AND PHOTOLUMINESCENCE SPECTRA OF PPV OLIGOMERS [J].
GRAHAM, SC ;
BRADLEY, DDC ;
FRIEND, RH ;
SPANGLER, C .
SYNTHETIC METALS, 1991, 41 (03) :1277-1280