SYNTHESIS AND X-RAY CRYSTAL STRUCTURAL-ANALYSIS OF A FULLY UNSATURATED TETRAPHOSPHOLE MACROCYCLE

被引：21

作者：

DESCHAMPS, E ^{[1
]}

RICARD, L ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,HETEROELEMENTS & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the 5,5'-bis(formyl)-2,2'-biphosphole 1 with the o-xylylidene bis-ylide 2 affords the 24-membered tetraphosphole macrocycle 3 in 60% yield; the X-ray crystal structure of 3 shows an all-trans disposition of the four lone pairs and a diameter of the central cavity of ca. 6 Angstrom.

引用

页码：1561 / 1561

页数：1

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