GENERALIZED SYNTHESIS OF CIS-DIOXORHENIUM(V) AND TRANS-DIOXORHENIUM(V) (BI)PYRIDYL COMPLEXES

被引：68

作者：

RAM, MS ^{[1
]}

HUPP, JT ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1021/ic00001a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Efficient new synthetic routes to trans-(O)2Re(py-X)2(py-Y)2+ and cis-(O)2Re(bpy-Y2)(py-X)2+ comlexes have been devised (py = pyridine; bpy = 2,2'-bipyridine). The new routes make use of labile cis-(O)2Re(py-X)2(I) species as preparative intermediates. The most useful new features of the synthetic chemistry are (1) the ability to prepare trans species containing electron-withdrawing substituents, (2) the ability to prepare mixed-ligand trans-dioxorhenium species, and (3) generalization of the cis-dioxorhenium preparation.

引用

页码：130 / 133

页数：4

共 21 条

[1]

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