A NOVEL SYNTHESIS OF HALOALKENES FROM ALDEHYDES WITH CARBON-CARBON COUPLING

被引：20

作者：

SATOH, T ^{[1
]}

ITOH, N ^{[1
]}

ONDA, KI ^{[1
]}

KITOH, Y ^{[1
]}

YAMAKAWA, K ^{[1
]}

机构：

[1] SCI UNIV TOKYO,FAC PHARMACEUT SCI,ICHIGAYA FUNAGAWARA MACHI,SHINJUKU KU,TOKYO 162,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 11期

关键词：

SULFOXIDE; 1-HALOALKYL ARYL SULFOXIDE; FLUOROALKENE; CHLOROALKENE; LIGAND EXCHANGE REACTION;

D O I：

10.1016/S0040-4039(00)91653-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alpha-halo beta-mesyloxy sulfoxides, easily synthesized from aldehydes and 1-haloalkyl aryl sulfoxides in two steps, with n-BuLi at -78-degrees-C gives haloalkenes in good yields.

引用

页码：1483 / 1484

页数：2

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