THE STRUCTURES OF SMALL IRON CARBON CLUSTER ANIONS - LINEAR TO PLANAR TO 3-DIMENSIONAL

被引：61

作者：

VON HELDEN, G ^{[1
]}

GOTTS, NG ^{[1
]}

MAITRE, P ^{[1
]}

BOWERS, MT ^{[1
]}

机构：

[1] UNIV PARIS 11, CHIM THEOR LAB, BATIMENT 490, F-91405 ORSAY, FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 227卷 / 06期

关键词：

D O I：

10.1016/0009-2614(94)00871-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structures of small mixed iron carbon cluster anions, Fe(n)C(m)- (n = 1, 2, 3 and m = 2-8) have been studied using gas phase ion chromatography. In the one iron atom case, results show a competition between linear structures and two-dimensional (planar) clusters. The two iron atom clusters, on the other hand, are pure monocyclic rings with the two iron atoms nearest neighbors. The three iron species are three-dimensional, and several possible structures are evaluated. In all cases the carbon atoms maintain a continuous chain and no carbon dimers are observed that would be characteristic of MetCar precursors.

引用

页码：601 / 608

页数：8

共 36 条

[1] VIBRATIONALLY RESOLVED SPECTRA OF C2-C-11 BY ANION PHOTOELECTRON-SPECTROSCOPY [J].