ANION INCLUSION BY A CALIX[4]ARENE COMPLEX - A CONTRAST BETWEEN TETRANUCLEAR GOLD(I) AND COPPER(I) COMPLEXES

被引：72

作者：

XU, W ^{[1
]}

ROURKE, JP ^{[1
]}

VITTAL, JJ ^{[1
]}

PUDDEPHATT, RJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000145

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tetradentate ligand, L, derived from a bowl-shaped calix[4]resorcinarene by incorporation of four phosphonite donors, has been used in the synthesis of several tetragold(I) and tetracopper(I) complexes, such as [L(AuCl)4] and [pyH]+[LCu4(mu-Cl)4(mu3-Cl)]-; the halide inclusion found for the copper complexes is unique in calixarene chemistry.

引用

页码：145 / 147

页数：3

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