LACTONIZATION OF OLEFINS MEDIATED BY MN(OAC)3 - A SONOCHEMICAL APPROACH

被引：53

作者：

ALLEGRETTI, M ^{[1
]}

DANNIBALE, A ^{[1
]}

TROGOLO, C ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

来源：

TETRAHEDRON | 1993年 / 49卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(01)81559-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of lactonization of olefins with carboxyalkyl radicals and Mn(OAc)3 was carried out under ultrasound irradiation at low temperatures Good yields of lactones were obtained in short reaction times. In sonochemical conditions, reoxidation of Mn(II) occurred, allowing the development of a lactonization procedure with a catalytic amount of Mn(III).

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页码：10705 / 10714

页数：10

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