DYNAMICS OF THE HETEROGENEOUS CATALYTIC-OXIDATION OF ETHANOL .1. ANALYSIS OF EXPERIMENTAL BIFURCATION DIAGRAMS

被引：14

作者：

JAEGER, NI

OTTENSMEYER, R

PLATH, PJ

ENGELHERBERT, H

机构：

[1] Institut für Angewandte und Physikalische Chemie, Universität Bremen, D-2800 Bremen 33, Bibliothekstraße

[2] Sektion Physik, Humboldt-Universität Berlin, 1040 Berlin

来源：

CHEMICAL ENGINEERING SCIENCE | 1990年 / 45卷 / 04期

关键词：

D O I：

10.1016/0009-2509(90)85017-8

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Experimental bifurcation diagrams for the heterogeneous catalytic oxidation of ethanol on a supported palladium catalyst are presented, depending on the oxygen or the ethanol content in the feed as control parameters. The identification of the bifurcations leads to a proposal for the formal construction of a mathematical model following Sheintuch and Luss (1985, Chem. Engng Sci. 40, 1653-1664; 1987a, Chem. Engng Sci. 42, 41-52; 1987b, Chem. Engng Sci. 42, 233-243). The identification of a global Hopf bifurcation in the experimental system requires an extension of their model. © 1990.

引用

页码：947 / 953

页数：7

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