TEMPERATURE-DEPENDENCE OF THE KINETICS OF THE REACTION AL+O2-]ALO+O

被引：42

作者：

GARLAND, NL

NELSON, HH

机构：

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 191卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(92)85299-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temperature and pressure dependence of the rate constant for the reaction Al + O2 has been measured by observing both Al disappearance and AlO appearance. No pressure dependence is observed from 10 to 100 Torr total pressure of Ar at room temperature. Over the range 298-1083 K, a fit to the measured data yields the expression k(T) = (1.62 +/- 0.13) x 10(-10) cm3 s-1 exp [(-0.16 +/- 0.08) kcal mol-1/RT].

引用

页码：269 / 272

页数：4

共 22 条

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