C71H2 CYCLOPROPANES AND ANNULENES - SYNTHESIS AND CHARACTERIZATION

被引:63
作者
SMITH, AB
STRONGIN, RM
BRARD, L
FURST, GT
ROMANOW, WJ
OWENS, KG
GOLDSCHMIDT, RJ
机构
[1] UNIV PENN,MONELL CHEM SENSES CTR,PHILADELPHIA,PA 19104
[2] DREXEL UNIV,DEPT CHEM,PHILADELPHIA,PA 19104
关键词
D O I
10.1039/c39940002187
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Addition of diazomethane to a toluene solution of C-70 affords a mixture of isomeric pyrazolines, which, upon photolysis, furnish two isomeric C71H2 cyclopropanes;thermolysis of the mixture produces two isomeric annulenes.
引用
收藏
页码:2187 / 2188
页数:2
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