THE ALKYLATION AND ACYLATION OF GLYCALS VIA AN INITIALIZING ELECTROCHEMICAL STEP

被引：16

作者：

FISCHER, S ^{[1
]}

HAMANN, CH ^{[1
]}

机构：

[1] CARL VON OSSIETZKY UNIV,FACHBEREICH CHEM,D-26111 OLDENBURG,GERMANY

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1080/07328309508002075

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The method of electrochemically induced formation of ether and ester derivatives of saturated mono- and disaccharides was applied to 1,2-unsaturated monosaccharides (D-glycals). The influence of the supporting electrolyte on the product distribution was investigated by variation of the cation. To provide data for comparison, alkylation was also carried out chemically in the presence of different bases, e.g. LiH and NaH.

引用

页码：327 / 339

页数：13

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