CHIRAL CROWN-ETHERS INCORPORATING D-GLUCOSE

被引：36

作者：

KANAKAMMA, PP

MANI, NS

MAITRA, U

NAIR, V

机构：

[1] CSIR,REG RES LAB,DIV ORGAN CHEM,TRIVANDRUM 695019,KERALA,INDIA

[2] INDIAN INST SCI,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 18期

关键词：

D O I：

10.1039/p19950002339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel class of crown ether derivatives incorporating D-glucose and poly(ethylene glycol) units has been synthesized from allyl alpha-D-glucopyranoside by a simple and efficient strategy. The complexing properties of these compounds with alkali metal cations and ammonium ion have been evaluated by Cram's picrate method. Catalytic activity of macrocycle 2 in asymmetric Michael addition reaction was also studied. The average cavity size of these macrocycles was determined by the application of the MMX programme.

引用

页码：2339 / 2344

页数：6

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