HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF [HN(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)]

被引：92

作者：

BONAVIA, G

DEBORD, J

HAUSHALTER, RC

ROSE, D

ZUBIETA, J

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

[2] NEC RES INST,PRINCETON,NJ 08540

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 11期

关键词：

D O I：

10.1021/cm00059a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrothermal reactions of VCl4 with phosphorous acid H3PO3, in the presence of the appropriate organoamine, yield new examples of the oxovanadium(IV)-phosphite class of materials, [HN(Me)(CH2CH2)(2)N(Me)H] [(VO)(4)(OH)(2)(HPO3)(4)] (1), [H2N(CH2CH2)(2)NH2] [(VO)(3)(HPO3)(4)(H2O)(2)] (2), and [VO(HPO3)(H2O)] (3). The 3-D framework structure adopted by 3 is illustrated.

引用

页码：1995 / &

共 27 条

[1] ZIRCONIUM PHOSPHITE (3,3',5,5'-TETRAMETHYLBIPHENYL)DIPHOSPHONATE, A MICROPOROUS, LAYERED, INORGANIC-ORGANIC POLYMER [J].