CATALYTIC ASYMMETRIC HYDROGENATION OF ACTIVATED KETO COMPOUNDS BY SOME HOMOGENEOUS AND SILICA-SUPPORTED DI(MU-CARBOXYLATO)BIS(AMINOPHOSPHINEPHOSPHINITE)DIRHODIUM COMPLEXES

被引：21

作者：

CARPENTIER, JF

AGBOSSOU, F

MORTREUX, A

机构：

[1] Laboratoire de Catalyse Hétérogène et Homogène, groupe de Chimie Organique Appliquée, URA CNRS 402, Ecole Nationale Supérieure de Chimie de Lille

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 01期

关键词：

D O I：

10.1016/0957-4166(94)00346-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New soluble and silica-supported rhodium complexes have been synthesized and tested as catalyst precursors for the enantioselective hydrogenation of alpha-ketoesters and an alpha-ketoamide. The homogeneous catalysts have been found to be efficient in terms of activity and asymmetric induction (up to 94% enantiomeric excess), On the other hand, the heterogenized systems exhibited lower performances and were gradually deactivated.

引用

页码：39 / 42

页数：4

共 16 条

[1] SYNTHESIS AND REACTIVITY OF RHODIUM(I) AND IRIDIUM(I) COMPLEXES OF THE DIANIONS OF 2,3-PYRAZINEDICARBOXYLIC AND 2,5-PYRAZINEDICARBOXYLIC ACID
BAYON, JC
NET, G
REAL, J
RASMUSSEN, PG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 385 (03) : 409 - 415
[2] BROGER EA, Patent No. 218970
[3] CEREGHETTI M, Patent No. 398132
[4] HARTLEY FR, 1987, CHEM METAL CARBON BO, V4, P1163
[5] HARTLEY FR, 1985, SUPPORTED METAL COMP
[6] NEW CHIRAL MIXED AMPP LIGANDS AND THEIR USE IN ASYMMETRIC HYDROGENATION OF ACTIVATED KETONES ON RHODIUM CATALYSTS
HATAT, C
KOKEL, N
MORTREUX, A
PETIT, F
[J]. TETRAHEDRON LETTERS, 1990, 31 (29) : 4139 - 4142
[7] HETFLEJS J, 1986, STUDIES SURFACE SCI, V27, P497
[8] HETFLEJS J, 1990, STUDIES SURFACE SCI, V55, P2803
[9] RHODIUM COMPLEXES CONTAINING 1-(4-PYRIDYLMETHYLENE)-4-ALKOXYANILINES AS LIGANDS - CRYSTAL-STRUCTURE OF AN UNUSUAL SQUARE-PLANAR CLUSTER OF 64 ELECTRONS, RH4(OOCCH3)4(CO)4(NC5H4CH=NC6H4OC14H29)4
LAHOZ, FJ
MARTIN, A
ESTERUELAS, MA
SOLA, E
SERRANO, JL
ORO, LA
[J]. ORGANOMETALLICS, 1991, 10 (06) : 1794 - 1799
[10] CATIONIC BINAP-RU(II) HALIDE-COMPLEXES - HIGHLY EFFICIENT CATALYSTS FOR STEREOSELECTIVE ASYMMETRIC HYDROGENATION OF ALPHA-FUNCTIONALIZED AND BETA-FUNCTIONALIZED KETONES
MASHIMA, K
KUSANO, KH
SATO, N
MATSUMURA, Y
NOZAKI, K
KUMOBAYASHI, H
SAYO, N
HORI, Y
ISHIZAKI, T
AKUTAGAWA, S
TAKAYA, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (11) : 3064 - 3076

← 1 2 →