ALKYLCOBALT CARBONYLS .10. CO ACTIVATION AND PHASE-TRANSFER-ACTIVE COORDINATION SITES IN ORGANOCOBALT CARBONYLS - MECHANISM OF THE REACTION OF BENZYL HALIDES AND TETRACARBONYLCOBALTATE(-I)

被引：23

作者：

HAASZ, F

BARTIK, T

GALAMB, V

PALYI, G

机构：

[1] HUNGARIAN ACAD SCI, PETROCHEM RES GRP, H-8201 VESZPREM, HUNGARY

[2] ALKALOIDA CHEM CO, H-4440 TISZAVASVARI, HUNGARY

[3] EOTVOS LORAND UNIV, INST GEN & INORGAN CHEM, H-1088 BUDAPEST, HUNGARY

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 10期

关键词：

D O I：

10.1021/om00160a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(4’-Halomethyl-1’,2’-benzo)-15-crown-5 (RX, 1; X = Cl (a), I (b)) compounds were reacted with Na-[Co(CO)4] (2). The corresponding η1-RC(O)Co(CO)4 (5), η1-RCo(CO)4 (6), and η3-RCo(CO)3 (7) derivatives were obtained through intermediates [(η5-RX)Na] [Co(CO)4] (3) and [(η5-Na+)RC(O)Co(CO)3(X-)] (4). The reactions leading to 7 from 1 were found to be reversible. Derivatives of 4 and 5 were prepared by monosubstitution with PPh3, giving 8 and 9, respectively. The reversibility of the reaction of PhCH2Cl with 2 was also demonstrated. © 1990, American Chemical Society. All rights reserved.

引用

页码：2773 / 2779

页数：7

共 94 条

[1] METHOD FOR PREPARING GLASS CAPILLARY COLUMNS FOR GAS-CHROMATOGRAPHY [J].