DETAILED STRUCTURAL INVESTIGATIONS OF HIGHLY ALIGNED LB STRUCTURES OF THIOPHENE DERIVATIVES

被引：8

作者：

SCHMELZER, M ^{[1
]}

BURGHARD, M ^{[1
]}

BAUERLE, P ^{[1
]}

ROTH, S ^{[1
]}

机构：

[1] UNIV STUTTGART,INST ORGAN CHEM,D-70569 STUTTGART,GERMANY

来源：

SYNTHETIC METALS | 1993年 / 61卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(93)91204-F

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We investigated Langmuir-Blodgett (LB) films of the molecule 3-thienylpentadecanoic acid (3TC15). Polarization-dependent Fourier transform infrared (FT-IR) spectroscopy and surface plasmon resonance (SPR) experiments were performed and the results indicate that the molecules are oriented with their long axis upright on the substrate with a weak tilt of 10-degrees. The thiophene moiety occupies an area per molecule which allows a partial interpenetration of adjacent monolayers. The detected monolayer thickness of 2.33 nm is in good agreement with the model of interpenetrating layers.

引用

页码：97 / 100

页数：4

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