SYNTHESIS OF BRIDGED DICYCLOOCTATETRAENES AND ALKYNYLCYCLOOCTATETRAENES BY PALLADIUM-CATALYZED COUPLING REACTIONS

被引：16

作者：

SIESEL, DA ^{[1
]}

STALEY, SW ^{[1
]}

机构：

[1] CARNEGIE MELLON UNIV,DEPT CHEM,4400 5TH AVE,PITTSBURGH,PA 15213

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)79199-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bridged dicyctooctatetraenes have been synthesized by the palladium-catalized coupling of distannanes with bromocycloocatetraene by employing the ligands tri(2-furyl)phosphine and triphenylarsine. The coupling of bromocyclooctatetraene with terminal alkynes is compared to couplings with alkynylstannanes for the preparation of alkynylcyclooctatetraenes.

引用

页码：3679 / 3682

页数：4

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