SYNTHESIS OF ORGANOURANIUM(V) COMPOUNDS BY OXIDATION OF NEUTRAL TETRAVALENT PRECURSORS - CRYSTAL-STRUCTURES OF [U(ETA-C(5)ME(5))(NME(2))(3)(OC4H8][BPH(4)] AND [U(ETA-C(5)ME(5))(2)(NET(2))(2)][BPH(4)], THE FIRST CATIONIC URANIUM(V) COMPLEXES

被引：34

作者：

BOISSON, C

BERTHET, JC

LANCE, M

NIERLICH, M

VIGNER, J

EPHRITIKHINE, M

机构：

[1] CE SACLAY,CEA,CHIM URANIUM LAB,SERV CHIM MOLEC,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

[2] CE SACLAY,CEA,CRISTALLOG LAB,SERV CHIM MOLEC,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

10.1039/c39950000543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cationic organouranium(v) compounds [U(eta-C(5)Me(5))(NMe(2))(3)(thf)][BPh(4)] 1, [U(eta-C(5)Me(5))(2)(NEt(2))(2)][BPh(4)] 2 and [U(eta-C8H8)(NEt(2))(2)(thf)][BPh(4)] 3, were synthesized by oxidation of the corresponding neutral U-IV precursors using AgBPh(4); the neutral complex [U(eta-C8H8)(eta-C5H5)(NEt(2))(2)] 4 was isolated from the reaction of [U(eta-C8H8)(NEt(2))(2)] with Tl(eta-C5H5).

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页码：543 / 544

页数：2

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