METHYL FORMATE SYNTHESIS BY HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE IN THE PRESENCE OF METHANOL

被引：71

作者：

JESSOP, PG

HSIAO, Y

IKARIYA, T

NOYORI, R

机构：

[1] RES DEV CORP JAPAN,ERATO MOLEC CATALYSIS PROJECT,TOYOTA 47003,JAPAN

[2] NAGOYA UNIV,DEPT CHEM,NAGOYA,AICHI 46401,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of methanol in the homogeneous ruthenium-catalysed hydrogenation of supercritical carbon dioxide to formic acid results in thermal esterification, producing methyl formate in higher yields and at lower temperatures than previously reported.

引用

页码：707 / 708

页数：2

共 14 条

[1] HOMOGENEOUS CATALYSTS FOR CARBON-DIOXIDE HYDROGEN ACTIVATION - ALKYL FORMATE PRODUCTION USING ANIONIC RUTHENIUM CARBONYL CLUSTERS AS CATALYSTS [J].

DARENSBOURG, DJ ;

OVALLES, C ;

PALA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5937-5939

[2] ANIONIC GROUP-6B METAL-CARBONYLS AS HOMOGENEOUS CATALYSTS FOR CARBON-DIOXIDE HYDROGEN ACTIVATION - THE PRODUCTION OF ALKYL FORMATES [J].

DARENSBOURG, DJ ;

OVALLES, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) :3750-3754

[3] CONVERSION OF CO2, H-2, AND ALCOHOLS INTO FORMATE ESTERS USING ANIONIC IRON CARBONYL HYDRIDES [J].

EVANS, GO ;

NEWELL, CJ .

INORGANICA CHIMICA ACTA, 1978, 31 (01) :L387-L389

[4] HETEROBIMETALLIC METHYLENEBIS(DIPHENYLPHOSPHINE) COMPLEXES - SYNTHESIS, STRUCTURE AND REACTIONS OF A MIXED PALLADIUM-MANGANESE SYSTEM [J].

HOSKINS, BF ;

STEEN, RJ ;

TURNEY, TW .

INORGANICA CHIMICA ACTA-LETTERS, 1983, 77 (02) :L69-L71

[5]

IKARIYA T, 1993, Patent No. 5274721

[6] SYNTHESIS OF FORMATES FROM ALCOHOLS, CARBON-DIOXIDE, AND HYDROGEN CATALYZED BY A COMBINATION OF GROUP-8 TRANSITION-METAL COMPLEXES AND TERTIARY-AMINES [J].

INOUE, Y ;

SASAKI, Y ;

HASHIMOTO, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (17) :718-719

[7] CATALYTIC PRODUCTION OF DIMETHYLFORMAMIDE FROM SUPERCRITICAL CARBON-DIOXIDE [J].

JESSOP, PG ;

HSIAO, Y ;

IKARIYA, T ;

NOYORI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) :8851-8852

[8] HOMOGENEOUS CATALYTIC-HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE [J].

JESSOP, PG ;

IKARIYA, T ;

NOYORI, R .

NATURE, 1994, 368 (6468) :231-233

[9]

JESSOP PG, UNPUB

[10]

KOLOMNIK.IS, 1972, B ACAD SCI USSR CH+, P2329

← 1 2 →