A STUDY OF THE ABSOLUTE PHOTOABSORPTION, PHOTOIONIZATION AND PHOTODISSOCIATION CROSS-SECTIONS AND THE PHOTOIONIZATION QUANTUM EFFICIENCY OF OXYGEN FROM THE IONIZATION THRESHOLD TO 490 ANGSTROM

被引：74

作者：

HOLLAND, DMP

SHAW, DA

MCSWEENEY, SM

MACDONALD, MA

HOPKIRK, A

HAYES, MA

机构：

[1] SERC Daresbury Laboratory, Warrington

来源：

CHEMICAL PHYSICS | 1993年 / 173卷 / 02期

关键词：

D O I：

10.1016/0301-0104(93)80148-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absolute photoabsorption, photoionization and photodissociation cross sections and the photoionization quantum efficiency of oxygen have been measured using a double ion chamber and monochromated synchrotron radiation. In addition to structure associated with well established Rydberg series, some new features have been observed which are interpreted in terms of transitions into Rydberg states converging onto the 3 2PI(u) ionization threshold. The photoionization quantum efficiency measurements indicate that the decay of Rydberg states by dissociation into neutral products is a significant de-excitation route, particularly for the low vibrational members of the H 3PI(u). state. A sum rule analysis has been carried out by combining the present absolute photoabsorption measurements with similar data covering the remaining wavelength regions.

引用

页码：315 / 331

页数：17

共 76 条

[1] HIGH-RESOLUTION INNER-VALENCE UV PHOTOELECTRON-SPECTRA OF THE O2 MOLECULE AND CONFIGURATION-INTERACTION CALCULATIONS OF 2-PI-U STATES BETWEEN 20 AND 26 EV [J].