SYNTHESIS AND STRUCTURE OF THE FIRST TRANSITION-METAL BORYLENE COMPLEXES

被引：103

作者：

BRAUNSCHWEIG, H

WAGNER, T

机构：

[1] Institut Für Anorganische Chemie, Technischen Hochschule, Aachen

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 07期

关键词：

BORON COMPOUNDS; COMPLEXES WITH BORON LIGANDS; MANGANESE COMPOUNDS;

D O I：

10.1002/anie.199508251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stable borylene‐bridged Mn2 complexes 1 and 2 are formed in the reaction of K[(η5‐C5H4R)‐Mn(SiMePh2)(CO)2] with the diboranes(4) B2X2Cl2. The mechanism of formation still remains to be clarified. The molecular structure of 1 (R = H) shows similarities with dimetallacyclopropane derivatives. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：825 / 826

页数：2

共 13 条

[1]

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[2]

Biffar W., 1980, ANGEW CHEM, V92, P63

[3]

CHISHOLM MH, 1983, COMPREHENSIVE COORDI, V2, P161

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