STRUCTURE ELUCIDATION OF A GLYCOSIDE OF 2-BETA,3-BETA-23-TRIHYDROXY-16-OXOOLEAN-12-EN-28-OIC ACID FROM BELLIS-BERNARDII USING MASS-SPECTROMETRY FOR THE SUGAR SEQUENCE DETERMINATION

被引：10

作者：

SCHOPKE, T

THIELE, H

WRAY, V

NIMTZ, M

HILLER, K

机构：

[1] Humboldt-Vniversitat zu Berlin, Fachbereich Pharmazie, D-13086 Berlin

[2] Gesellschaft für Biotechnologische Forschung mbH, D-38124 Braunschweig

来源：

JOURNAL OF NATURAL PRODUCTS-LLOYDIA | 1995年 / 58卷 / 01期

关键词：

D O I：

10.1021/np50115a026

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

The structure of a novel saponin, possessing an unusual aglycone named bellisonic acid and isolated from whole plants of Bellis bernardii, has been elucidated by modern ms and nmr techniques as 3-O-alpha-L-rhamnopyranosyl-2 beta,3 beta,23-trihydroxy-16-oxoolean-12-en-28-oic acid 28-alpha-L-rhamnopyranosyl(1-->3)-O-beta-D-xylopyranosyl(1-->4)-alpha-L-rhamnopyranosyl(1-->2)-beta-D-fucopyranoside [1]. Ms procedures of general applicability allowed unambiguous sugar sequence determination from very small amounts of material.

引用

页码：152 / 155

页数：4

共 11 条

[1]

DORCHAI R. O., 1968, TETRAHEDRON, V24, P1377, DOI 10.1016/0040-4020(68)88089-5

[2]

HARA S, 1987, CHEM PHARM BULL, V35, P501

[3]

HILLER K, 1988, PHARMAZIE, V43, P850

[4]

JANSSON PE, 1976, J CHEM SOC CHEM COMM, P1

[5] TRITERPENOID SAPONINS FROM BELLIS-SYLVESTRIS .1. STRUCTURES OF THE MAJOR DEACYLSAPONINS [J].

SCHOPKE, T ;

HILLER, K ;

WRAY, V ;

KOPPEL, KD ;

YAMASAKI, K ;

KASAI, R .

JOURNAL OF NATURAL PRODUCTS, 1994, 57 (09) :1279-1282

[6]

SCHOPKE T, 1990, PHARMAZIE, V45, P870

[7] BAYOGENIN AND ASTEROGENIC ACID GLYCOSIDES FROM BELLIS-PERENNIS [J].

SCHOPKE, T ;

WRAY, V ;

KUNATH, A ;

HILLER, K .

PHYTOCHEMISTRY, 1992, 31 (07) :2555-2557

[8] BELLISSAPONIN-BA1 AND BELLISSAPONIN-BA2 - ACYLATED SAPONINS FROM BELLIS-PERENNIS [J].

SCHOPKE, T ;

WRAY, V ;

RZAZEWSKA, B ;

HILLER, K .

PHYTOCHEMISTRY, 1991, 30 (02) :627-631

[9]

ZENG I, 1990, YAOXUE XUEBAO, V25, P515

[10] 2 TRITERPENOIDS FROM ROOTS OF GLYCYRRHIZA-YUNNANENSIS [J].

ZENG, L ;

ZHANG, RY ;

WANG, D ;

LOU, ZC .

PHYTOCHEMISTRY, 1990, 29 (11) :3605-3609

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