1ST PHOTOSENSITIZED ENANTIODIFFERENTIATING POLAR ADDITION - ANTI-MARKOVNIKOV METHANOL ADDITION TO 1,1-DIPHENYLPROPENE

被引：25

作者：

INOUE, Y

OKANO, T

YAMASAKI, N

TAI, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 08期

关键词：

D O I：

10.1039/c39930000718

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiodifferentiating methanol addition to 1,1-diphenylpropene sensitized by chiral naphthalene (di) carboxylates gave optically active 1,1-diphenyl-2-methoxypropane in optical yields up to 27%, indicating the intervention of an intimately interacting exciplex or contact ion pair.

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页码：718 / 720

页数：3

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