X-RAY CRYSTALLOGRAPHIC STUDY OF FLUORINE ATOM EFFECT ON GUEST ORIENTATION INSIDE THE ALPHA-CYCLODEXTRIN CAVITY

被引：28

作者：

SHIBAKAMI, M ^{[1
]}

SEKIYA, A ^{[1
]}

机构：

[1] NATL CHEM LAB IND,HIGASHI 1-1,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期

关键词：

D O I：

10.1039/c39920001742

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray crystallographic studies of alpha-cyclodextrin (alpha-CD)-2- and -4-fluorophenol complexes indicate that the fluorine atom determines the guest orientations inside the alpha-CD cavity in both complexes, and accordingly that the hydroxy groups of 4-FC6H4OH and 2-FC6H4OH are located inside and outside the cavity, respectively.

引用

页码：1742 / 1743

页数：2

共 4 条

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HARATA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (06) :1416-1424

[2] INTERMOLECULAR INTERACTIONS OF THE C-F BOND - THE CRYSTALLOGRAPHIC ENVIRONMENT OF FLUORINATED CARBOXYLIC-ACIDS AND RELATED STRUCTURES [J].

MURRAYRUST, P ;

STALLINGS, WC ;

MONTI, CT ;

PRESTON, RK ;

GLUSKER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (10) :3206-3214

[3]

SHIBAKAMI M, 1991, CHEM EXPRESS, V6, P837

[4]

SHIBAKAMI M, IN PRESS B CHEM SOC

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