PHOTOCATALYTIC DEHYDROGENATION OF METHANOL USING [IRH(SNCL3)5]3- COMPLEX

被引：18

作者：

MAKITA, K ^{[1
]}

NOMURA, K ^{[1
]}

SAITO, Y ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT IND CHEM,3-1 HONGO 7 CHOME,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 89卷 / 1-2期

关键词：

DEHYDROGENATION; IRIDIUM; METHANOL; PHOTOCATALYSIS; TIN(II)-COORDINATED COMPLEXES;

D O I：

10.1016/0304-5102(93)E0315-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High photocatalytic activity for methanol dehydrogenation has been revealed with (NEt4)3[IrH(SnCl3)5], yielding dihydrogen and dimethoxymethane in a stoichiometric ratio. The important role of [IrH(SnCl3)5]3- species in photocatalysis for alcohol dehydrogenation with tin(II)-coordinated iridium(III) complexes was confirmed; the reaction rates were enhanced by adding SnCl2, LiCl and HCl to this complex in appropriate amounts.

引用

页码：143 / 150

页数：8

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