INFRARED STUDY OF COMPLEXES BETWEEN IRON, SALICYLALDEHYDE BENZOYL HYDRAZONE AND 7 ANALOGOUS DERIVATIVES

被引：16

作者：

COLOMA, C ^{[1
]}

DOUCET, JP ^{[1
]}

COSSEBARBI, A ^{[1
]}

机构：

[1] UNIV PARIS 07,INST TOPOL & DYNAM SYST,CNRS,URA 34,F-75232 PARIS 05,FRANCE

来源：

TRANSITION METAL CHEMISTRY | 1995年 / 20卷 / 04期

关键词：

D O I：

10.1007/BF00139124

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An i.r. study of Fe complexes prepared from salicylaldehyde benzoyl hydrazone and seven similar chelating agents allowed the assignment of some iron-ligand bands. The amide I and Phi-O band shifts indicate that the ligand O atoms are directly linked to Fe. The analogy between Fe-II and Fe-III complexes in the mid-i.r. range and the chiefly identical frequencies in the far-i.r. range provide evidence that oxidation of Fe-II has occurred. The bands directly involved in complexation are shifted compared to the free hydrazones, and all are medium or weak.

引用

页码：338 / 343

页数：6

共 26 条

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