(2S,6S,8S)-2,8-DIMETHYL-1,7-DIOXASPIRO[5.5]UNDECANE - A NATURAL SPIROACETAL LACKING ANOMERIC STABILIZATION

被引：17

作者：

CHEN, JJ

FLETCHER, MT

KITCHING, W

机构：

[1] Department of Chemistry, The University of Queensland, Brisbane

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 04期

关键词：

D O I：

10.1016/0957-4166(95)00107-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The absolute stereochemistry of the non-anomerically stabilised spiroacetal, (Z,Z)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane, 4 which is a significant component of the pheromonal gland secretion of the cucumber fly (Bactrocera cucumis French) is shown to be (2S,6S,8S) by synthesis of its enantiomer, and chiral gas chromatographic analyses.

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页码：967 / 972

页数：6

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