REGIOSELECTIVITY AND STEREOSELECTIVITY OF CYCLOADDITIONS OF TRIFLUOROMETHYLATED AZOMETHINE YLIDE

被引：29

作者：

TANAKA, K

NAGATANI, S

OHSUGA, M

MITSUHASHI, K

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 02期

关键词：

D O I：

10.1246/bcsj.67.589

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifluoromethylated azomethine ylide 1, generated in situ by the conrotatory ring opening of cis-2-benzoyl-1-methyl-3-trifluoromethylaziridine, cycloadded with both electron-deficient and -rich monosubstituted olefins to give exclusively the corresponding 3-substituted pyrrolidines. This high regioselectivity is discussed in connection with the interaction between 1-LUMO and olefin-HOMO.

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页码：589 / 591

页数：3

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