THIOOXALIC ACID 2-AMIDE-1-HYDRAZIDE-2-HYDRAZONE - A NEW ZWITTERION COMPOUND

被引:5
作者
DEHNE, H
SCHEUNEMANN, A
MICHALIK, M
HARTUNG, H
HEINEMANN, F
KIBBEL, HU
机构
[1] UNIV ROSTOCK EV,INST ORGAN KATALYSEFORSCH,D-18055 ROSTOCK,GERMANY
[2] UNIV HALLE WITTENBERG,FACHBEREICH CHEM,D-06108 HALLE,GERMANY
[3] UNIV ROSTOCK EV,WEITERBLDG GESELL,D-18059 ROSTOCK,GERMANY
来源
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 86卷 / 1-4期
关键词
HYDRAZINOLYSIS OF CYANODITHIOFORMATE; THIOOXALIC ACID 2-AMIDE-1-HYDRAZIDE-2-HYDRAZONE; THIOOXALIC ACID HYDRAZIDE AMIDE HYDRAZONE; X-RAY ANALYSIS; NMR DATA;
D O I
10.1080/10426509408018401
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of sodium cyanodithioformate (NaSC(S)CN.3DMF) with hydrazine hydrate gives thiooxalic acid 2-amide-1-hydrazide-2-hydrazone in good yields. Spectroscopic data, X-ray analysis, and the chemical behaviour prove the zwitterionic structure of this compound.
引用
收藏
页码:177 / 179
页数:3
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