THE OBSERVATION OF PSEUDOROTATING LITHIUM AND POTASSIUM CLUSTERS LI-5 AND K-7 IN AN ADAMANTANE MATRIX

被引：11

作者：

HOWARD, JA

JOLY, HA

JONES, R

EDWARDS, PP

SINGER, RJ

LOGAN, DE

机构：

[1] UNIV BIRMINGHAM, SCH CHEM, BIRMINGHAM B15 2TT, W MIDLANDS, ENGLAND

[2] UNIV CAMBRIDGE, CHEM LAB, CAMBRIDGE CB2 1EW, ENGLAND

[3] UNIV OXFORD, PHYS CHEM LAB, OXFORD OX1 3OZ, ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 204卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(93)85616-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The pseudorotating clusters, Li-5 and K7, have been identified in an adamantane matrix by EPR spectroscopy. These new clusters were synthesised by depositing the parent alkali metal atoms at 77 K in the hydrocarbon matrix followed by careful annealing to temperatures above 200 K.

引用

页码：128 / 132

页数：5

共 23 条

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